Diaquabis(3-nitrobenzoato-κO 1)bis[1H-5-(3-pyridyl)-3-(4-pyridyl)-1H-1,2,4-triazole-κN 5]cobalt(II) dihydrate
نویسندگان
چکیده
In the centrosymmetric title compound, [Co(C(7)H(4)NO(4))(2)(C(12)H(9)N(5))(2)(H(2)O)(2)]·2H(2)O, the Co(II) atom, located on an inversion center, is coordinated by two N atoms [Co-N = 2.155 (3) Å] and four O atoms [Co-O = 2.099 (2)-2.117 (3) Å] in a distorted octa-hedral geometry. Inter-molecular N-H⋯O, O-H⋯N and O-H⋯O hydrogen bonds link the components into a three-dimensional supramolecular framework.
منابع مشابه
Diaqua[3,5-bis(4-pyridyl)-1H-1,2,4-triazole-κN 3](pyridine-2,6-dicarboxylato-κ3 O 2,N,O 6)nickel(II)
In the title compound, [Ni(C(7)H(3)NO(4))(C(12)H(9)N(5))(H(2)O)(2)], the Ni(II) atom is coordinated in a distorted octa-hedral geometry by one N and two O atoms from a pyridine-2,6-dicarboxyl-ate ligand, one N atom from a 3,5-bis-(4-pyrid-yl)-1H-1,2,4-triazole ligand in equatorial positions and two water mol-ecules in axial positions. The crystal packing is consolidated by inter-molecular O-H⋯O...
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010